Nuclear Physics and Atomic Energy

Ядерна фізика та енергетика
Nuclear Physics and Atomic Energy

  ISSN: 1818-331X (Print), 2074-0565 (Online)
  Publisher: Institute for Nuclear Research of the National Academy of Sciences of Ukraine
  Languages: Ukrainian, English
  Periodicity: 4 times per year

  Open access peer reviewed journal


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Nucl. Phys. At. Energy 2025, volume 26, issue 4, pages 373-377.
Section: Engineering and Methods of Experiment.
Received: 10.09.2025; Accepted: 26.11.2025; Published online: 29.12.2025.
PDF Full text (ua)
https://doi.org/10.15407/jnpae2025.04.373

Radiation resistant plastic scintillator with 4,4′-di-tert-butylbiphenyl

O. V. Yelisieieva*, D. A. Yelisieiev, Yu. О. Нurkalenko, P. М. Zhmurin, V. D. Alekseev

Institute of Scintillation Materials, STC "Institute for Single Crystals", National Academy of Sciences of Ukraine, Kharkiv, Ukraine

*Corresponding author. E-mail address: osvidlo@i.ua

Abstract: The article considers the possibility of creating a radiation-resistant plastic scintillator based on polystyrene using a dialkyl derivative of biphenyl – 4,4′-di-tert-butylbiphenyl. Two types of scintillators were obtained: in the first, 4,4′-di-tert-butylbiphenyl was used as an activator, and in the second as a diffusion enhancer. The spectral-luminescent and scintillation properties of the obtained materials were studied, and their radiation resistance, as well as microhardness, were determined. A plastic scintillator containing 20 wt. % 4,4′-di-tert-butylbiphenyl was created, the light output half-attenuation dose of which is 163 kGy.

Keywords: 4,4′-di-tert-butylbiphenyl, plastic scintillator, radiation resistance, light output, microhardness.

References:

1. S. Chatrchyan et al. (The CMS Collaboration). The CMS experiment at the CERN LHC. JINST 3 (2008) S08004. https://doi.org/10.1088/1748-0221/3/08/S08004

2. G. Aad et al. (The ATLAS Collaboration). The ATLAS experiment at the CERN Large Hadron Collider. JINST 3 (2008) S08003. https://doi.org/10.1088/1748-0221/3/08/S08003

3. A.A. Alves Jr. et al. (The LHCb Collaboration). The LHCb detector at the LHC. JINST 3 (2008) S08005. https://doi.org/10.1088/1748-0221/3/08/S08005

4. Kuraray's Scintillation Materials. https://www-he.scphys.kyoto-u.ac.jp/~nakaya/T2K280m/FGD/kuraray_fiber.pdf

5. Plastic Scintillators: General Purpose. Luxium Solutions. https://luxiumsolutions.com/radiation-detection-scintillators/plastic-scintillators/bc400-bc404-bc408-bc412-bc416

6. B.V. Hrynyov, V.G. Senchyshyn. Plastic Scintillators (Kharkiv: Akta, 2003) 324 p. (Ukr)

7. V.G. Senchishin et al. Radiation resistance investigation of SCSN-81T, BC-408, UPS923A and UPS98RH plastic scintillators. Funct. Mater. 10(2) (2003) 281. http://functmaterials.org.ua/contents/10-2/FM102-30.pdf

8. P.N. Zhmurin et al. Radiation-hard plastic scintillator with increased mechanical strength. Funct. Mater. 22(2) (2015) 280. https://doi.org/10.15407/fm22.02.280

9. F. Markley et al. Development of radiation hard scintillators. Radiat. Phys. Chem. 41 (1-2) (1993) 135. https://doi.org/10.1016/0969-806X(93)90050-5

10. E.S. Velmozhnaya et al. Investigation of the behavior of gadolinium complexes in plastic scintillators. Funct. Mater. 20(4) (2013) 494. https://doi.org/10.15407/fm20.04.494

11. E.S. Velmozhnaya et al. The new radiation-hard plastic scintillators with diffusion enhancers and 3-hydroxyflavone derivatives. Funct. Mater. 23(4) (2016) 650. https://doi.org/10.15407/fm23.04.463

12. V. Baranov et al. Effects of neutron radiation on the optical and structural properties of blue and green emitting plastic scintillators. Nucl. Instrum. Methods B 436 (2018) 236. https://doi.org/10.1016/j.nimb.2018.10.002

13. J. Wetzel et al. Using LEDs to stimulate the recovery of radiation damage to plastic scintillators. Nucl. Instrum. Methods B 395 (2017) 13. https://doi.org/10.1016/j.nimb.2017.01.081

14. L.D. Maslennikova et al. Physical Chemistry of Polymers (Kyiv: National Aviation University Publishing House "NAU-druk", 2009) 312 p. (Ukr)

15. A.F. Adadurov et al. Efficiency improvement of polystyrene-based plastic scintillators. Funct. Mater. 16(4) (2009) 475. http://functmaterials.org.ua/contents/16-4/fm164-08.pdf

16. S. Melkhanova et al. Thermochemical studies of 4-tert-butylbiphenyl and 4,4′-di-tert-butylbiphenyl. J. Chem. Thermodyn. 41 (2009) 651. https://doi.org/10.1016/j.jct.2008.12.015

17. M.I. Aizatskyi et al. State and prospects of the linac of nuclear-physics complex with energy of electrons up to 100 MeV. Probl. At. Sci. Technol. 3(91) (2014) 60. https://vant.kipt.kharkov.ua/ARTICLE/VANT_2014_3/article_2014_3_60.pdf

18. J.B. Birks. The Theory and Practice of Scintillation Counting (London: Pergamon Press, 1964) 664 р. https://www.elsevier.com/books/the-theory-and-practice-of-scintillation-counting/birks/978-0-08-010472-0