Ядерна фізика та енергетика Nuclear Physics and Atomic Energy   ISSN: 1818-331X (Print), 2074-0565 (Online)   Publisher: Institute for Nuclear Research of the National Academy of Sciences of Ukraine   Languages: Ukrainian, English   Periodicity: 4 times per year   Open access peer reviewed journal

Full text (en)

V. I. Slisenko, O. A. Vasylkevych^*

Institute for Nuclear Research, National Academy of Sciences of Ukraine, Kyiv, Ukraine

^*Corresponding author. E-mail address: a.vas@i.ua

Abstract: The results of studying the dynamics of molecules of solutions of fullerene C₆₀ in benzene and toluene are presented. The studies were carried out by the method of quasi-elastic scattering of slow neutrons. The following were determined: the total self-diffusion coefficient D, its collective D_coll and single-particle D_s-p contributions, and molecule relaxation time τ₀ before and after the dissolution of fullerene. It is necessary to pay attention to the fact that in our case a kind of neutron contrast experiment takes place. The significant difference (more than ten times) in the cross-sections for an incoherent scattering of neutrons by hydrogen and carbon nuclei made it possible to obtain diffusion parameters that characterize the dynamics of solvent molecules exclusively. It turned out that the intensity of diffusion movements of solvent molecules is almost ten times higher than the mobility of fullerene molecules.

Keywords: fullerenes, quasi-elastic scattering of slow neutrons, self-diffusion coefficient, single-particle and collective components of the self-diffusion coefficient.

1. V.N. Bezmelnitsyn et al. Fullerenes in solutions. Physics Uspekhi 41(11) (1998) 1091. http://dx.doi.org/10.1070/PU1998v041n11ABEH000502

2. A.V. Eletskii, B.M. Smirnov. Fullerenes and carbon structures. Physics-Uspekhi 38(9) (1995) 935. https://doi.org/10.3367/UFNr.0165.199509a.0977

3. L.A. Bulavin et al. Neutron Spectroscopy of Condensed Environments (Kyiv: Akademperiodyka, 2005) 635 p. (Ukr)

4. A.P. Voiter et al. Multichannel analyser for the neutron time-of-flight spectrometer. Yaderna Fizyka ta Energetyka (Nucl. Phys. At. Energy) 11(1) (2010) 90. (Ukr) https://jnpae.kinr.kyiv.ua/11.1/Articles_PDF/jnpae-2010-11-0090-Voiter.pdf

5. D. Dubois et al. Electroreduction of Buckminsterfullerene, C₆₀, in aprotic solvents. Solvent, supporting electrolyte, and temperature effects. J. Phys. Chem. 96 (1992) 7137. https://doi.org/10.1021/j100196a056