Nuclear Physics and Atomic Energy

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Nuclear Physics and Atomic Energy

  ISSN: 1818-331X (Print), 2074-0565 (Online)
  Publisher: Institute for Nuclear Research of the National Academy of Sciences of Ukraine
  Languages: Ukrainian, English, Russian
  Periodicity: 4 times per year

  Open access peer reviewed journal

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Nucl. Phys. At. Energy 2018, volume 19, issue 1, pages 43-47.
Section: Radiation Physics.
Received: 08.12.2017; Accepted: 22.03.2018; Published online: 12.05.2018.
PDF Full text (en)
https://doi.org/10.15407/jnpae2018.01.043

Structure, morphology, thermal and conductivity properties of gel electrolyte system based on polyvinyl chloride and LiClO4

V. V. Klepko1, V. I. Slisenko2, K. M. Sukhyy3,*, S. D. Nesin1, V. L. Kovalenko3,4, Y. O. Serhiienko3, I. V. Sukha3

1 Institute for Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine
2 Institute for Nuclear Research, National Academy of Sciences of Ukraine, Kyiv, Ukraine
3 Ukrainian State University of Chemical Technology, Dnipro, Ukraine
4 Federal State Educational Institution of Higher Education "Vyatka State University", Kirov, Russia

*Corresponding author. E-mail address: tor_bt@udhtu.edu.ua; ksukhyy@gmail.com

Abstract: The dynamics of atoms and molecules in gel electrolyte based on polyvinyl chloride and a solution of LiClO4 in propylene carbonate was studied by the method of quasielastic scattering of slow neutrons. The coefficients of self-diffusion of atoms and molecules are determined and a possible variant of the mechanism of charge transport in this system is proposed.

Keywords: solid polymer electrolytes, polyvinyl chloride, X-ray scattering, calorimetric scattering, quasi-elastic neutron scattering.

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