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New composite fibres for natural and waste waters decontamination from cesium radionuclides
Yu. V. Bondar1,*, S. V. Kuzenko1, V. M. Slyvinsky1, T. I. Koromyslichenko2Abstract: New composite adsorbent based on modified polyacrylonitrile fibers is synthesized by in situ deposition of potassium-nickel ferrocyanide layer on the fibers’ surface. It is shown that the ferrocyanide phase forms a compact homogeneous layer on the fibers’ surface consisted of rounded nanoaggregates (∼ 40 - 50 nm). Composite fibers are chemically stable in both acidic and alkaline solutions. Sorption experiments have demonstrated that synthesized fibers are high-selective adsorbents and can be used for the purification of natural waters and high-salt solutions from cesium radionuclides.
Keywords: composite adsorbent, polyacrylonitrile fibers, potassium-nickel ferrocyanide, selectivity, 137Cs, high-salt solutions, liquid radioactive waste.1. I.V. Tananaev, G.B. Saifer, Yu.Ya. Kharitonov et al., Ferrocyanide Chemistry, Moskva: Nauka (1971), 320 p. (Rus)
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